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Indiana Administrative Code (Last Updated: December 20, 2016) |
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Title 327. WATER POLLUTION CONTROL DIVISION |
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Article 327IAC2. WATER QUALITY STANDARDS |
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Rule 327IAC2-1.5. Water Quality Standards Applicable to All State Waters Within the Great Lakes System |
Section 327IAC2-1.5-8. Minimum surface water quality criteria
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(a) All surface water quality criteria in this section, except those provided in subsection (b)(1), will cease to be applicable when the stream flows are less than the applicable stream design flow for the particular criterion as determined under 327 IAC 5-2-11.4.
(b) The following are minimum surface water quality conditions:
(1) All surface waters within the Great Lakes system at all times and at all places, including waters within the mixing zone, shall meet the minimum conditions of being free from substances, materials, floating debris, oil, or scum attributable to municipal, industrial, agricultural, and other land use practices, or other discharges that do any of the following:
(A) Will settle to form putrescent or otherwise objectionable deposits.
(B) Are in amounts sufficient to be unsightly or deleterious.
(C) Produce:
(i) color;
(ii) visible oil sheen;
(iii) odor; or
(iv) other conditions;
in such degree as to create a nuisance.
(D) Are in concentrations or combinations that will cause or contribute to the growth of aquatic plants or algae to such degree as to:
(i) create a nuisance;
(ii) be unsightly; or
(iii) otherwise impair the designated uses.
(E) Are in amounts sufficient to be acutely toxic to, or to otherwise severely injure or kill, aquatic life, other animals, plants, or humans. To assure protection of aquatic life, the waters shall meet the following requirements:
(i) Concentrations of toxic substances shall not exceed the CMC or SMC outside the zone of initial dilution or the final acute value (FAV = 2 (CMC) or 2 (SMC)) in the undiluted discharge unless, for a discharge to a receiving stream or Lake Michigan, an alternate mixing zone demonstration is conducted and approved in accordance with 327 IAC 5-2-11.4(b)(4), in which case, the CMC or SMC shall be met outside the applicable alternate mixing zone:
(AA) for certain substances, a CMC is established and set forth in subdivision (3), Table 8-1 (which table incorporates subdivision (4), Table 8-2), and subdivision (5);
(BB) for substances for which a CMC is not specified in subdivision (3), Table 8-1, or subdivision (5), a CMC shall be calculated by the commissioner using the procedures in section 11 of this rule, or, if the minimum data requirements to calculate a CMC are not met, an SMC shall be calculated using the procedures in section 12 of this rule; and
(CC) the CMC or SMC determined under subitem (AA) or (BB) may be modified on a site-specific basis to reflect local conditions in accordance with section 16 of this rule.
(ii) A discharge shall not cause acute toxicity, as measured by whole effluent toxicity tests, at any point in the waterbody. Compliance with this criterion shall be demonstrated if a discharge does not exceed one and zero-tenths (1.0) TUa in the undiluted discharge. For a discharge into a receiving stream or Lake Michigan, for which an alternate mixing zone demonstration is conducted and approved in accordance with 327 IAC 5-2-11.4(b)(4), compliance with this criterion shall be demonstrated if three-tenths (0.3) TUa is not exceeded outside the applicable alternate mixing zone.
This clause shall not apply to the chemical control of plants and animals when that control is performed in compliance with approval conditions specified by the Indiana department of natural resources as provided by IC 14-22-9.
(2) At all times, all surface waters outside of the applicable mixing zones determined in accordance with section 7 of this rule shall be free of substances in concentrations that, on the basis of available scientific data, are believed to be sufficient to injure, be chronically toxic to, or be carcinogenic, mutagenic, or teratogenic to humans, animals, aquatic life, or plants. To assure protection against the adverse effects identified in this subdivision, a toxic substance or pollutant shall not be present in such waters in concentrations that exceed the most stringent of the following:
(A) A CCC or an SCC to protect aquatic life from chronic toxic effects as follows:
(i) For certain substances, a CCC is established and set forth in subdivision (3), Table 8-1 (which table incorporates subdivision (4), Table 8-2), and subdivision (5).
(ii) For substances for which a CCC is not specified in subdivision (3), Table 8-1, or subdivision (5), a CCC shall be calculated by the commissioner using the procedures in section 11 of this rule, or, if the minimum data requirements to calculate a CCC are not met, an SCC shall be calculated using the procedures in section 12 of this rule.
(iii) The CCC or SCC determined under item (i) or (ii) may be modified on a site-specific basis to reflect local conditions in accordance with section 16 of this rule.
(iv) To assure protection of aquatic life, a discharge shall not cause chronic toxicity, as measured by whole effluent toxicity tests, outside of the applicable mixing zone. Compliance with this criterion shall be demonstrated if the waterbody does not exceed one and zero-tenths (1.0) TUc at the edge of the mixing zone.
(B) An HNC or HNV to protect human health from adverse noncancer effects that may result from the consumption of aquatic organisms or drinking water from the waterbody determined as follows:
(i) For certain substances, an HNC is established and set forth in subdivision (6), Table 8-3.
(ii) For substances for which an HNC is not specified in subdivision (6), Table 8-3, an HNC shall be calculated by the commissioner using the procedures in section 14 of this rule, or, if the minimum data requirements to calculate an HNC are not met, an HNV shall be calculated using the procedures in section 14 of this rule.
(iii) The HNC or HNV determined under item (i) or (ii) may be modified on a site-specific basis to reflect local conditions in accordance with section 16 of this rule.
(iv) The HNC-nondrinking or HNV-nondrinking for a substance shall apply to all surface waters outside the applicable mixing zone for a discharge of that substance. The HNC-drinking or HNV-drinking shall apply at the point of the public water system intake.
(C) For carcinogenic substances, an HCC or HCV to protect human health from unacceptable cancer risk of greater than one (1) additional occurrence of cancer per one hundred thousand (100,000) population as follows:
(i) For certain substances, an HCC is established and set forth in subdivision (6), Table 8-3.
(ii) For substances for which an HCC is not specified in subdivision (6), Table 8-3, an HCC shall be calculated by the commissioner using the procedures in section 14 of this rule or, if the minimum data requirements to calculate an HCC are not met, an HCV shall be calculated using the procedures in section 14 of this rule.
(iii) The HCC or HCV determined under item (i) or (ii) may be modified on a site-specific basis to reflect local conditions in accordance with section 16 of this rule.
(iv) The HCC-nondrinking or HCV-nondrinking for a substance shall apply to all surface waters outside the applicable mixing zone for a discharge of that substance. The HCC-drinking or HCV-drinking shall apply at the point of the public water system intake.
(D) A WC to protect avian and mammalian wildlife populations from adverse effects that may result from the consumption of aquatic organisms or water from the waterbody as follows:
(i) For certain substances, a WC is established and set forth in subdivision (7), Table 8-4.
(ii) For substances for which a WC is not specified in subdivision (7), Table 8-4, a WC shall be calculated by the commissioner using the procedures in section 15 of this rule or, if the minimum data requirements to calculate a WC are not met, a WV may be calculated using the procedures in section 15 of this rule.
(iii) The WC or WV determined under item (i) or (ii) may be modified on a site-specific basis to reflect local conditions in accordance with section 16 of this rule.
(3) The following establishes surface water quality criteria for protection of aquatic life:
Table 8-1
Surface Water Quality Criteria for Protection of Aquatic Life[1]
CAS Number
Substances
CMC (Maximum) (μg/l)
CMC Conversion Factors
CCC (4-Day Average) (μg/l)
CCC Conversion Factors
Metals (dissolved)[2]
7440382
Arsenic (III)
WER[3](339.8)
1.000
WER[3](147.9)
1.000
7440439
Cadmium
WER[3](e(1.128 [ln(hardness)]-3.6867))
1.136672-[(ln hardness) (0.041838)]
WER[3](e(0.7852 [ln(hardness)]-2.715))
1.101672-[(ln hardness) (0.041838)]
7440473
Chromium (III)
WER[3](e(0.819 [ln(hardness)]+3.7256))
0.316
WER[3](e(0.819 [ln(hardness)]+0.6848))
0.860
7440473
Chromium (VI)
WER[3](16.02)
0.982
WER[3](10.98)
0.962
7440508
Copper
WER[3](e(0.9422 [ln(hardness)]-1.700))
0.960
WER[3](e(0.8545 [ln(hardness)]-1.702))
0.960
7439976
Mercury
WER[3](1.694)
0.85
WER[3](0.9081)
0.85
7440020
Nickel
WER[3](e(0.846 [ln(hardness)]+2.255))
0.998
WER[3](e(0.846 [ln(hardness)]+0.0584))
0.997
7782492
Selenium
5
0.922
7440666
Zinc
WER[3](e(0.8473 [ln(hardness)]+0.884))
0.978
WER[3](e(0.8473 [ln(hardness)]+0.884))
0.986
Organics (total)
60571
Dieldrin
0.24
NA
0.056
NA
72208
Endrin
0.086
NA
0.036
NA
56382
Parathion
0.065
NA
0.013
NA
87865
Pentachlorophenol [4]
e(1.005[pH]-4.869)
NA
e(1.005[pH]-5.134)
NA
Other Substances
Chloride
[6]
NA
[6]
NA
Chlorine (total residual)
19
NA
11
NA
Chlorine (intermittent, total residual) [5]
200
NA
NA
57125
Cyanide (free)
22
NA
5.2
NA
[1] Aquatic organisms should not be affected unacceptably if the four (4) day average concentration of any substance in this table does not exceed the CCC more than once every three (3) years on the average and if the one (1) hour average concentration does not exceed the CMC more than once every three (3) years on the average, except possibly where a commercially or recreationally important species is very sensitive.
[2] The CMC and CCC columns of this table contain total recoverable metals criteria (numeric and hardness-based). The criterion for the dissolved metal is calculated by multiplying the appropriate conversion factor by the CMC or CCC. This dissolved CMC or CCC shall be rounded to two (2) significant digits, except when the criteria are used as intermediate values in a calculation, such as in the calculation of water quality-based effluent limitations (WQBELs).
[3] A value of one (1) shall be used for the WER unless an alternate value is established under section 16 of this rule.
[4] A CMC and CCC calculated for pentachlorophenol using the equation in this table shall be rounded to two (2) significant digits, except when the criteria are used as intermediate values in a calculation, such as in the calculation of WQBELs.
[5] To be considered an intermittent discharge, total residual chlorine shall not be detected in the discharge for a period of more than forty (40) minutes in duration, and such periods shall be separated by at least five (5) hours.
[6] The CMC and CCC for this substance are established in subdivision (5).
(4) The following establishes dissolved CMCs and CCCs for certain metals at selected hardness values calculated from the equations and conversion factors in subdivision (3), Table 8-1 and using a value of one (1) for the WER, where applicable:
Table 8-2
Metals Concentrations in Micrograms Per Liter; Hardness in Milligrams Per Liter CaCO31
Arsenic (III)
Cadmium
Chromium (III)
Chromium (VI)
Copper
Mercury
Nickel
Selenium
Zinc
Hardness
CMC
CCC
CMC
CCC
CMC
CCC
CMC
CCC
CMC
CCC
CMC
CCC
CMC
CCC
CMC
CCC
CMC
CCC
50
340
150
2.0
1.3
320
42
16
11
7.0
5.0
1.4
0.77
260
29
─
4.6
65
66
100
340
150
4.3
2.2
570
74
16
11
13
9.0
1.4
0.77
470
52
─
4.6
120
120
150
340
150
6.6
3.0
790
100
16
11
20
13
1.4
0.77
660
73
─
4.6
170
170
200
340
150
9.0
3.7
1,000
130
16
11
26
16
1.4
0.77
840
93
─
4.6
210
210
250
340
150
12
4.4
1,200
160
16
11
32
20
1.4
0.77
1,000
110
─
4.6
250
260
300
340
150
14
5.0
1,400
180
16
11
38
23
1.4
0.77
1,200
130
─
4.6
300
300
350
340
150
17
5.6
1,600
210
16
11
44
26
1.4
0.77
1,400
150
─
4.6
340
340
400
340
150
19
6.2
1,800
230
16
11
50
29
1.4
0.77
1,500
170
─
4.6
380
380
450
340
150
22
6.8
2,000
250
16
11
55
32
1.4
0.77
1,700
190
─
4.6
420
420
500
340
150
24
7.3
2,100
280
16
11
61
35
1.4
0.77
1,800
200
─
4.6
460
460
[1] The dissolved metals criteria in this table have been rounded to two (2) significant digits in accordance with subdivision (3), Table 8-1. The equations and conversion factors in subdivision (3), Table 8-1 shall be used instead of the criteria in this table when dissolved metals criteria are used as intermediate values in a calculation, such as in the calculation of WQBELs.
(5) The following establishes surface water quality criteria for chloride for protection of aquatic life:
(A) The following provides the CMC for chloride as a function of hardness (in mg/l as CaCO3) and sulfate (in mg/l) in surface waters:
C = 287.8 (hardness)0.205797 (sulfate)-0.07452
Where: C = chloride CMC (maximum) in mg/l.
(B) The following provides the CCC for chloride as a function of hardness (in mg/l as CaCO3) and sulfate (in mg/l) in surface waters:
C = 177.87 (hardness)0.205797 (sulfate)-0.07452
Where: C = chloride CCC (4-Day Average) in mg/l.
(C) The CMC and CCC for chloride calculated from the equations in this subdivision shall be rounded to the nearest whole numbers, except when the criteria are used as intermediate values in a calculation, such as in the calculation of WQBELs.
(D) The following establishes the CMC for chloride in mg/l at selected concentrations of hardness and sulfate, with the understanding that the equation in clause (A) shall be used instead of the criteria in this clause when chloride criteria are used as intermediate values in a calculation, such as in the calculation of WQBELs:
Table 8-2a
Hardness (mg/l)
Sulfate (mg/l)
50
100
150
200
250
300
350
400
450
500
15
526
607
660
700
733
761
785
807
827
845
20
515
594
646
685
717
745
769
790
809
827
25
506
584
635
674
705
732
756
777
796
813
50
481
555
603
640
670
695
718
738
756
773
100
457
527
573
608
636
660
682
701
718
734
150
443
511
556
589
617
641
661
680
697
712
200
434
500
544
577
604
627
647
665
682
697
250
427
492
535
567
594
617
637
654
671
685
300
421
485
528
560
586
609
628
646
661
676
350
416
480
522
553
579
602
621
638
654
668
400
412
475
516
548
574
596
615
632
647
662
450
408
471
512
543
569
590
609
626
642
656
500
405
467
508
539
564
586
605
622
637
651
(E) The following establishes the CCC for chloride in mg/l at selected concentrations of hardness and sulfate, with the understanding that the equation in clause (B) shall be used instead of the criteria in this clause when chloride criteria are used as intermediate values in a calculation, such as in the calculation of WQBELs:
Table 8-2b
Hardness (mg/l)
Sulfate (mg/l)
50
100
150
200
250
300
350
400
450
500
15
325
375
408
433
453
470
485
499
511
522
20
318
367
399
423
443
460
475
488
500
511
25
313
361
392
416
436
453
467
480
492
503
50
297
343
373
395
414
430
444
456
467
477
100
282
326
354
375
393
408
421
433
444
453
150
274
316
343
364
381
396
409
420
430
440
200
268
309
336
357
373
388
400
411
421
431
250
264
304
331
351
367
381
394
404
414
423
300
260
300
326
346
362
376
388
399
409
418
350
257
297
322
342
358
372
384
394
404
413
400
255
294
319
339
355
368
380
391
400
409
450
252
291
316
336
351
365
377
387
397
405
500
250
289
314
333
349
362
374
384
394
402
(6) The following establishes surface water quality criteria for protection of human health:
Table 8-3
Surface Water Quality Criteria for Protection of Human Health[1]
Human Noncancer Criteria (HNC)
Human Cancer Criteria (HCC)
CAS Number
Substances
Drinking (μg/l)
Nondrinking (μg/l)
Drinking (μg/l)
Nondrinking (μg/l)
Metals (total recoverable)
7439976
Mercury (including methylmercury)
0.0018
0.0018
Organics (total)
71432
Benzene
19
510
12
310
57749
Chlordane
0.0014
0.0014
0.00025
0.00025
108907
Chlorobenzene
470
3,200
50293
DDT
0.002
0.002
0.00015
0.00015
60571
Dieldrin
0.00041
0.00041
6.5 × 10-6
6.5 × 10-6
105679
2,4-dimethylphenol
450
8,700
51285
2,4-dinitrophenol
55
2,800
118741
Hexachlorobenzene
0.046
0.046
0.00045
0.00045
67721
Hexachloroethane
6
7.6
5.3
6.7
58899
Lindane
0.47
0.5
75092
Methylene chloride
1,600
90,000
47
2600
1336363
PCBs (class)
6.8 × 10-6
6.8 × 10-6
1746016
2,3,7,8-TCDD (dioxin)
6.7 × 10-8
6.7 × 10-8
8.6 × 10-9
8.6 × 10-9
108883
Toluene
5,600
51,000
8001352
Toxaphene
6.8 × 10-5
6.8 × 10-5
79016
Trichloroethylene
29
370
Other Substances
57125
Cyanide (total)
600
48,000
[1]The HNC and HCC are thirty (30) day average criteria.
(7) The following establishes surface water quality criteria for protection of wildlife:
Table 8-4
Surface Water Quality Criteria for Protection of Wildlife[1]
CAS Number
Substances
Wildlife Criteria (μg/l)
Metals (total recoverable)
7439976
Mercury (including methylmercury)
0.0013
Organics (total)
50293
DDT and metabolites
1.1 × 10-5
1336363
PCBs (class)
1.2 × 10-4
1746016
2, 3, 7, 8-TCDD (dioxin)
3.1 × 10-9
[1]The WC are thirty (30) day average criteria.
(c) This subsection establishes minimum surface water quality criteria for aquatic life. In addition to the criteria in subsection (b), this subsection ensures conditions necessary for the maintenance of a well-balanced aquatic community. The following conditions are applicable at any point in the waters outside of the applicable mixing zone, as determined in accordance with section 7 of this rule:
(1) There shall be no substances that:
(A) impart unpalatable flavor to food fish; or
(B) result in offensive odors in the vicinity of the water.
(2) No pH values below six (6.0) or above nine (9.0), except daily fluctuations that:
(A) exceed pH nine (9.0); and
(B) are correlated with photosynthetic activity;
shall be permitted.
(3) Concentrations of dissolved oxygen shall:
(A) average at least five (5.0) milligrams per liter per calendar day; and
(B) not be less than four (4.0) milligrams per liter at any time.
(4) The following are conditions for temperature:
(A) There shall be no abnormal temperature changes that may adversely affect aquatic life unless caused by natural conditions.
(B) The normal daily and seasonal temperature fluctuations that existed before the addition of heat due to other than natural causes shall be maintained.
(C) Water temperatures shall not exceed the maximum limits in the following table during more than one percent (1%) of the hours in the twelve (12) month period ending with any month. At no time shall the water temperature at such locations exceed the maximum limits in the following table by more than three (3) degrees Fahrenheit (one and seven-tenths (1.7) degrees Celsius):
Table 8-5
Maximum Instream Water Temperatures
Month
St. Joseph River Tributary to Lake Michigan Upstream of the Twin Branch Dam °F(°C)
All Other Indiana Streams in the Great Lakes System °F(°C)
January
50 (10)
50 (10)
February
50 (10)
50 (10)
March
55 (12.8)
60 (15.6)
April
65 (18.3)
70 (21.1)
May
75 (23.9)
80 (26.7)
June
85 (29.4)
90 (32.2)
July
85 (29.4)
90 (32.2)
August
85 (29.4)
90 (32.2)
September
84 (29.4)
90 (32.2)
October
70 (21.1)
78 (25.5)
November
60 (15.6)
70 (21.1)
December
50 (10)
57 (14.0)
(D) The following temperature criteria shall apply to Lake Michigan:
(i) In all receiving waters, the points of measurement normally shall be in the first meter below the surface at such depths necessary to avoid thin layer surface warming due to extreme ambient air temperatures, but, where required to determine the true distribution of heated wastes and natural variations in water temperatures, measurements shall be at a greater depth and at several depths as a thermal profile.
(ii) There shall be no abnormal temperature changes so as to be injurious to fish, wildlife, or other aquatic life, or the growth or propagation thereof. In addition, plume interaction with the bottom shall:
(AA) be minimized; and
(BB) not injuriously affect fish, shellfish, and wildlife spawning or nursery areas.
(iii) The normal daily and seasonal temperature fluctuations that existed before the addition of heat shall be maintained.
(iv) At any time and at a maximum distance of a one thousand (1,000) foot arc inscribed from a fixed point adjacent to the discharge or as agreed upon by the commissioner and federal regulatory agencies, the following shall apply:
(AA) The receiving water temperature shall not be more than three (3) degrees Fahrenheit (one and seven-tenths (1.7) degrees Celsius) above the existing natural water temperature.
(BB) Thermal discharges to Lake Michigan shall comply with the following maximum temperature requirements:
(aa) Thermal discharges to Lake Michigan shall not raise the maximum temperature in the receiving water above those listed in the following table, except to the extent the permittee adequately demonstrates that the exceedance is caused by the water temperature of the intake water:
Table 8-6
Maximum Water Temperatures
Month
°F(°C)
January
45 (7)
February
45 (7)
March
45 (7)
April
55 (13)
May
60 (16)
June
70 (21)
July
80 (27)
August
80 (27)
September
80 (27)
October
65 (18)
November
60 (16)
December
50 (10)
(bb) If the permittee demonstrates that the intake water temperature is within three (3) degrees Fahrenheit below an applicable maximum temperature under subitem (aa), Table 8-6, then not more than a three (3) degree Fahrenheit exceedance of the maximum water temperature shall be permitted.
(v) The facilities described as follows that discharge into the open waters of Lake Michigan shall be limited to the amount essential for blowdown in the operation of a closed cycle cooling facility:
(AA) All facilities that have new waste heat discharges exceeding a daily average of five-tenths (0.5) billion British thermal units per hour. As used in this item, "new waste heat discharge" means a discharge that had not begun operations as of February 11, 1972.
(BB) All facilities with existing waste heat discharges that increase the quantity of waste heat discharged by more than a daily average of five-tenths (0.5) billion British thermal units per hour.
(vi) Water intakes shall be designed and located to minimize entrainment and damage to desirable organisms. Requirements may vary depending upon local conditions, but, in general, intakes shall:
(AA) have minimum water velocity; and
(BB) not be located in spawning or nursery areas of important fishes.
Water velocity at screens and other exclusion devices shall also be at a minimum.
(vii) Discharges other than those now in existence shall be such that the thermal plumes do not overlap or intersect.
(viii) Facilities discharging more than a daily average of five-tenths (0.5) billion British thermal units of waste heat shall:
(AA) continuously record intake and discharge temperature and flow; and
(BB) make those records available to the public or regulatory agencies upon request.
(5) The following criteria shall be used to regulate ammonia:
(A) Concentrations of total ammonia (as N) shall not exceed the CMC outside the zone of initial dilution or the final acute value (FAV = 2 (CMC)) in the undiluted discharge unless, for a discharge to a receiving stream or Lake Michigan, an alternate mixing zone demonstration is conducted and approved in accordance with 327 IAC 5-2-11.4(b)(4), in which case, the CMC shall be met outside the applicable alternate mixing zone. The CMC of total ammonia (as N) is determined using the following equation:
Where:
FT
=
100.03(20-T)
FPH
=
1; when: 8 ≤ pH ≤ 9; or
; when: 6.5 ≤ pH ≤ 8
pKa
=
T
=
Temperature in °C
(B) The CCC of total ammonia (as N) is determined using the following equation:
Where:
FT
=
100.03(20-T)
FPH
=
1; when: 8 ≤ pH ≤ 9; or
; when: 6.5 ≤ pH ≤ 8
RATIO
=
13.5; when: 7.7 ≤ pH ≤ 9; or
; when: 6.5 ≤ pH ≤ 7.7
pKa
=
T
=
Temperature in °C
(C) The use of the equations in clause (A) results in the following CMCs for total ammonia (as N) at different temperatures and pHs:
Table 8-7
Criterion Maximum Concentrations for Total Ammonia (as N) Temperature (°C)
pH
0
5
10
15
20
25
30
6.5
28.48
26.61
25.23
24.26
23.64
23.32
23.29
6.6
27.68
25.87
24.53
23.59
22.98
22.68
22.65
6.7
26.74
24.99
23.69
22.78
22.20
21.92
21.90
6.8
25.64
23.96
22.72
21.85
21.30
21.03
21.01
6.9
24.37
22.78
21.60
20.78
20.26
20.01
20.00
7.0
22.95
21.45
20.35
19.58
19.09
18.86
18.86
7.1
21.38
19.98
18.96
18.24
17.80
17.59
17.60
7.2
19.68
18.40
17.46
16.81
16.40
16.22
16.24
7.3
17.90
16.73
15.88
15.29
14.93
14.78
14.81
7.4
16.06
15.02
14.26
13.74
13.42
13.30
13.35
7.5
14.23
13.31
12.64
12.19
11.92
11.81
11.88
7.6
12.44
11.65
11.07
10.67
10.45
10.37
10.45
7.7
10.75
10.06
9.569
9.238
9.052
9.003
9.088
7.8
9.177
8.597
8.181
7.907
7.760
7.734
7.830
7.9
7.753
7.268
6.924
6.701
6.589
6.584
6.689
8.0
6.496
6.095
5.813
5.636
5.555
5.569
5.683
8.1
5.171
4.857
4.639
4.508
4.457
4.486
4.602
8.2
4.119
3.873
3.707
3.612
3.584
3.625
3.743
8.3
3.283
3.092
2.967
2.900
2.891
2.942
3.061
8.4
2.618
2.472
2.379
2.335
2.340
2.399
2.519
8.5
2.091
1.979
1.911
1.886
1.903
1.968
2.089
8.6
1.672
1.588
1.540
1.529
1.555
1.625
1.747
8.7
1.339
1.277
1.246
1.246
1.279
1.353
1.475
8.8
1.075
1.030
1.011
1.021
1.060
1.137
1.260
8.9
0.8647
0.8336
0.8254
0.8418
0.8862
0.9650
1.088
9.0
0.6979
0.6777
0.6777
0.6998
0.7479
0.8286
0.9521
(D) The use of the equations in clause (B) results in the following CCCs for total ammonia (as N) at different temperatures and pHs:
Table 8-8
Criterion Continuous Concentrations for Total Ammonia (as N) Temperature (°C)
pH
0
5
10
15
20
25
30
6.5
2.473
2.310
2.191
2.106
2.052
2.025
2.022
6.6
2.473
2.311
2.191
2.107
2.053
2.026
2.023
6.7
2.473
2.311
2.191
2.107
2.054
2.027
2.025
6.8
2.473
2.311
2.192
2.108
2.055
2.028
2.027
6.9
2.474
2.312
2.193
2.109
2.056
2.030
2.030
7.0
2.474
2.312
2.193
2.110
2.058
2.033
2.033
7.1
2.475
2.313
2.195
2.112
2.060
2.036
2.037
7.2
2.475
2.314
2.196
2.114
2.063
2.040
2.043
7.3
2.476
2.315
2.198
2.116
2.066
2.044
2.050
7.4
2.477
2.317
2.200
2.119
2.070
2.050
2.058
7.5
2.478
2.319
2.202
2.123
2.075
2.058
2.069
7.6
2.480
2.321
2.206
2.128
2.082
2.067
2.082
7.7
2.450
2.294
2.181
2.106
2.063
2.052
2.071
7.8
2.092
1.959
1.865
1.802
1.769
1.763
1.785
7.9
1.767
1.657
1.578
1.527
1.502
1.501
1.525
8.0
1.481
1.389
1.325
1.285
1.266
1.269
1.295
8.1
1.179
1.107
1.057
1.027
1.016
1.022
1.049
8.2
0.9387
0.8828
0.8450
0.8232
0.8169
0.8263
0.8531
8.3
0.7481
0.7048
0.6762
0.6610
0.6589
0.6705
0.6976
8.4
0.5968
0.5634
0.5421
0.5321
0.5334
0.5468
0.5741
8.5
0.4766
0.4511
0.4357
0.4298
0.4337
0.4485
0.4760
8.6
0.3811
0.3619
0.3511
0.3485
0.3545
0.3704
0.3981
8.7
0.3052
0.2910
0.2839
0.2839
0.2916
0.3083
0.3362
8.8
0.2450
0.2347
0.2305
0.2326
0.2417
0.2591
0.2871
8.9
0.1971
0.1900
0.1881
0.1919
0.2020
0.2199
0.2480
9.0
0.1591
0.1545
0.1545
0.1595
0.1705
0.1889
0.2170
(d) This subsection establishes surface water quality for cold-water fish. The waters listed in section 5(a)(3) of this rule are designated as salmonid waters and shall be protected for cold-water fish. In addition to subsections (b) and (c), the following criteria are established to ensure conditions necessary for the maintenance of a well-balanced, cold-water fish community and are applicable at any point in the waters outside of the applicable mixing zone:
(1) Dissolved oxygen concentrations shall not be less than:
(A) six (6.0) milligrams per liter at any time; and
(B) seven (7.0) milligrams per liter in areas where spawning occurs during the spawning season and in areas used for imprinting during the time salmonids are being imprinted.
Dissolved oxygen concentrations in the open waters of Lake Michigan shall not be less than seven (7.0) milligrams per liter at any time.
(2) The maximum temperature rise above natural shall not exceed two (2) degrees Fahrenheit (one and one-tenth (1.1) degrees Celsius) at any time or place and, unless due to natural causes, the temperature shall not exceed the following:
(A) Seventy (70) degrees Fahrenheit (twenty-one and one-tenth (21.1) degrees Celsius) at any time.
(B) Sixty-five (65) degrees Fahrenheit (eighteen and three-tenths (18.3) degrees Celsius) during spawning or imprinting periods.
(e) This subsection establishes bacteriological quality for recreational uses during the recreational season as follows:
(1) The recreational season is defined as the months of April through October, inclusive.
(2) In addition to subsection (b), the criteria in this subsection shall be used to do the following:
(A) Evaluate waters for full body contact recreational uses.
(B) Establish wastewater treatment requirements.
(C) Establish effluent limits during the recreational season.
(3) For full body contact recreational uses, E. coli bacteria shall not exceed the following:
(A) One hundred twenty-five (125) per one hundred (100) milliliters as a geometric mean based on not less than five (5) samples equally spaced over a thirty (30) day period.
(B) Two hundred thirty-five (235) per one hundred (100) milliliters in any one (1) sample in a thirty (30) day period, except that in cases where there are at least ten (10) samples at a given site, up to ten percent (10%) of the samples may exceed two hundred thirty-five (235) cfu or MPN per one hundred (100) milliliters where:
(i) the E. coli exceedances are incidental and attributable solely to E. coli resulting from the discharge of treated wastewater from a wastewater treatment plant as defined at IC 13-11-2-258; and
(ii) the criterion in clause (A) is met.
However, a single sample shall be used for making beach notification and closure decisions.
If a geometric mean cannot be calculated because five (5) equally spaced samples are not available, then the criterion stated in clause (B) must be met.
(4) For demonstrating compliance with wastewater treatment requirements, sanitary wastewater dischargers shall ensure the following:
(A) The concentration of E. coli in the undiluted discharge does not exceed one hundred twenty-five (125) cfu or MPN per one hundred (100) milliliters as a geometric mean of the effluent samples taken in a calendar month.
(B) Not more than ten percent (10%) of all samples when not less than ten (10) samples are taken and analyzed for E. coli in a calendar month exceed two hundred thirty-five (235) cfu or MPN per one hundred (100) milliliters as a daily maximum. Under this clause, the calculation of ten percent (10%) of the samples taken shall be limited to the lowest whole number result.
(5) Effluent limits to implement the criteria in subdivision (3) during the recreational season shall be established in NPDES permits by incorporating the following that are to be applied to the undiluted discharge:
(A) The concentration of E. coli in the undiluted discharge shall not exceed one hundred twenty-five (125) cfu or MPN per one hundred (100) milliliters as a geometric mean of the effluent samples taken in a calendar month.
(B) Not more than ten percent (10%) of all samples in a calendar month exceed two hundred thirty-five (235) cfu or MPN per one hundred (100) milliliters as a daily maximum. Under this clause, the calculation of ten percent (10%) of the samples taken shall be limited to the lowest whole number result.
(f) This subsection establishes surface water quality for public water supply. In addition to subsection (b), the following criteria are established to protect the surface water quality at the point at which water is withdrawn for treatment for public supply:
(1) The coliform bacteria group shall not exceed the following:
(A) Five thousand (5,000) per one hundred (100) milliliters as a monthly average value (either MPN or MF count).
(B) Five thousand (5,000) per one hundred (100) milliliters in more than twenty percent (20%) of the samples examined during any month.
(C) Twenty thousand (20,000) per one hundred (100) milliliters in more than five percent (5%) of the samples examined during any month.
(2) Taste and odor producing substances, other than those naturally occurring, shall not interfere with the production of a finished water by conventional treatment consisting of the following:
(A) Coagulation.
(B) Sedimentation.
(C) Filtration.
(D) Disinfection.
(3) The concentrations of either chloride or sulfate shall not exceed two hundred fifty (250) milligrams per liter unless due to naturally occurring sources.
(4) The concentration of dissolved solids shall not exceed seven hundred fifty (750) milligrams per liter unless due to naturally occurring sources. A specific conductance of one thousand two hundred (1,200) micromhos per centimeter (at twenty-five (25) degrees Celsius) may be considered equivalent to a dissolved solids concentration of seven hundred fifty (750) milligrams per liter.
(5) Surface waters shall be considered acceptable for public water supply if radium-226 and strontium-90 are present in amounts not exceeding three (3) and ten (10) picocuries per liter, respectively. In the known absence of strontium-90 and alpha emitters, the water supply is acceptable when the gross beta concentrations do not exceed one thousand (1,000) picocuries per liter.
(6) The:
(A) combined concentration of nitrate-N and nitrite-N shall not exceed ten (10) milligrams per liter; and
(B) concentration of nitrite-N shall not exceed one (1) milligram per liter.
(7) Chemical constituents in the waters shall not be present in such levels as to prevent, after conventional treatment, meeting the drinking water standards contained in 327 IAC 8-2, due to other than natural causes.
(g) This subsection establishes surface water quality for industrial water supply. In addition to subsection (b), the criterion to ensure protection of water quality at the point at which water is withdrawn for use (either with or without treatment) for industrial cooling and processing is that, other than from naturally occurring sources, the dissolved solids shall not exceed seven hundred fifty (750) milligrams per liter at any time. A specific conductance of one thousand two hundred (1,200) micromhos per centimeter (at twenty-five (25) degrees Celsius) may be considered equivalent to a dissolved solids concentration of seven hundred fifty (750) milligrams per liter.
(h) This subsection establishes surface water quality for agricultural uses. The criteria to ensure water quality conditions necessary for agricultural use are the same as those in subsection (b).
(i) This subsection establishes surface water quality for limited uses. The quality of waters designated for limited uses under section 19(a) of this rule shall, at a minimum, meet the following criteria:
(1) The criteria contained in subsection (b).
(2) The criteria contained in subsection (e).
(3) The criteria contained in subsection (g).
(4) The waters must be aerobic at all times.
(5) Notwithstanding subdivisions (1) through (4), the quality of a limited use stream at the point where it becomes physically or chemically capable of supporting a higher use or at its interface with a higher use water segment shall meet the criteria that are applicable to the higher use water.
(j) Additional requirements for the open waters of Lake Michigan are as follows:
(1) In addition to complying with all other applicable subsections, open waters in Lake Michigan shall meet the following criteria:
Table 8-9
Additional Criteria for Lake Michigan
Parameters
Criteria
Dissolved oxygen
Dissolved oxygen concentrations shall not be less than seven (7.0) milligrams per liter at any time at all places outside the applicable mixing zone.
pH
No pH values below six (6.0) or above nine (9.0), except daily fluctuations that exceed pH 9.0 and are correlated with photosynthetic activity, shall be permitted.
Chloride
250 mg/l[1]
Phenols
See subsection (c)(1)
Sulfate
250 mg/l[1]
Total phosphorus
See 327 IAC 5-10-2
Total dissolved solids
750 mg/l[1]
Fluoride
1.0 mg/l[1]
Dissolved iron
300 μg/l[1]
[1] This criterion is established to minimize or prevent increased levels of this substance in Lake Michigan. For the purposes of establishing water quality-based effluent limitations based on this criterion, it shall be treated as a four (4) day average criterion.
(2) During each triennial review of the water quality standards, prior to preliminary adoption of revised rules, the department shall prepare a report for the water pollution control board on the monitoring data for the constituents in the following table (Table 8-10), as measured at the drinking water intakes in Lake Michigan. If these data indicate that the levels of the constituents are either increasing or exceed the levels in the table, the report shall provide available information on the known and potential causes of the increased levels of these parameters, the known and potential impacts on aquatic life, wildlife, and human health, and any recommended revisions of the criteria.
Table 8-10
Parameters
Levels
pH
7.5-8.5 s.u.
Chloride
Monthly average
15 mg/l
Daily maximum
20 mg/l
Sulfate
Monthly average
26 mg/l
Daily maximum
50 mg/l
Total phosphorus
Monthly average
0.03 mg/l
Daily maximum
0.04 mg/l
Total dissolved solids
Monthly average
172 mg/l
Daily maximum
200 mg/l
(Water Pollution Control Division; 327 IAC 2-1.5-8; filed Jan 14, 1997, 12:00 p.m.: 20 IR 1370; errata filed Aug 11, 1997, 4:15 p.m.: 20 IR 3376; filed Feb 14, 2005, 10:05 a.m.: 28 IR 2074; errata filed Apr 6, 2006, 2:48 p.m.: 29 IR 2546; filed Mar 18, 2008, 2:26 p.m.: 20080416-IR-327060573FRA; filed Jul 9, 2012, 2:54 p.m.: 20120808-IR-327110320FRA)